How is FeCl3 named using the charge of its iron ion?

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Because iron can form more than one type of cation, the nomenclature for its binary ionic compounds must specify the charge of the metal ion present.

In the compound FeCl3, the iron exists as an Fe3+ ion. According to systematic naming rules, this is designated as iron(III) chloride, where the Roman numeral (III) explicitly indicates the +3 charge of the iron ion.1

Alternatively, an older naming system uses suffixes to distinguish between the two common oxidation states of iron. In this system, the ion with the higher charge (+3) is given the suffix -ic, while the ion with the lower charge (+2) receives the suffix -ous. Consequently, FeCl3 is also commonly referred to as ferric chloride, whereas FeCl2 is known as ferrous chloride.12