How does resonance make the two oxygen-oxygen bonds in ozone equivalent?
In chemistry, the ambiguity regarding the location of double bonds in the ozone (O₃) molecule is resolved through a quantum mechanical phenomenon known as resonance.12
While individual Lewis structures may suggest distinct single and double bonds, the actual structure of the ozone molecule is a resonance hybrid—a blend of these contributing structures. Resonance acts as a blending process that spreads the double-bond character evenly across the participating atoms.132
As a result, the two oxygen-oxygen bonds in ozone are rendered equivalent, with each bond possessing a mixture of single-bond and double-bond character. This equivalence is reflected in the observed length and strength of the bonds, which are intermediate between those of a pure single bond and a pure double bond.12