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How does palladium chloride help oxidize ethylene into acetaldehyde?
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catalysis
Nanoparticles of a gold-palladium (yellow-blue) alloy supported on acid-treated carbon (gray) directly catalyzing hydrogen peroxide formation from hydrogen (white) and oxygen (red) while shutting off unwanted hydrogen peroxide decomposition.
The oxidation of ethylene to acetaldehyde is achieved through the Wacker process, which utilizes a two-component catalyst system consisting of palladium chloride () and copper chloride ().1
In this catalytic cycle, palladium chloride acts as the primary catalyst to facilitate the oxidation of ethylene. During the reaction, the palladium is repeatedly converted from its salt form to the free metal. The role of the copper chloride is to participate in the regeneration of the palladium salt from the metallic palladium, allowing the process to continue efficiently.2