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How does nitrogen dioxide react with water in a disproportionation reaction?
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oxide
Iron oxide (rust) on a bolt.
Nitrogen dioxide () reacts with water through a disproportionation reaction, a process in which the nitrogen atom is simultaneously oxidized and reduced. The specific products of this reaction depend on the temperature of the water:123
- In cold water: Nitrogen dioxide disproportionates to form a mixture of nitrous acid () and nitric acid ().
- At higher temperatures: The reaction produces nitric acid () and nitric oxide (). In this specific reaction, the nitrogen atom in the oxidation state is reduced to (in ) and oxidized to (in ), as shown in the following equation:123