How does ionic radius change down the alkaline-earth metal group?
The ionic radii of the alkaline-earth metals increase steadily as you move down the group in the periodic table. This trend is a direct result of the increasing size of the inner electron cores as the principal quantum number of the outermost orbitals increases.1
The following table illustrates the increase in the radius of the +2 ions (measured in angstroms) from beryllium to radium:
| Element | Ionic Radius (+2 ion, Å) |
| :--- | :--- |
| Beryllium (Be) | 0.31 |
| Magnesium (Mg) | 0.65 |
| Calcium (Ca) | 0.99 |
| Strontium (Sr) | 1.13 |
| Barium (Ba) | 1.35 |
| Radium (Ra) | 1.48 |
This steady growth in ionic size influences various chemical properties, including the ability of these ions to coordinate with other molecules and the strength of their bonding to ligands.12