How does helium-3 help form helium-4 in the proton-proton cycle?

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In the proton-proton cycle, helium-3 (3He) serves as a critical intermediate product that facilitates the formation of helium-4 (4He).

After hydrogen nuclei fuse to form deuterium and subsequently capture another proton to create helium-3, the cycle reaches a stage where helium-3 nuclei react with one another. In the most direct continuation of this chain, two helium-3 nuclei collide and fuse to produce one helium-4 nucleus and two protons. This reaction is represented as:12

3He+3He→4He+2(1H)

At equilibrium, helium-3 burns predominantly through this self-interaction because its reaction rate with hydrogen is low and the concentration of deuterium is negligible. This process is a fundamental step in the nuclear fusion reactions that power stars like the Sun, ultimately resulting in the synthesis of helium from hydrogen.12