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How does gallium react with acids and alkalis?

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Gallium is an amphoteric metal, meaning it can react as either an acid or a base depending on the environment.1

  • Reaction with Acids: Gallium reacts slowly with hydrochloric acid and other mineral acids to produce the gallium ion (Ga3+) and various salts. Notably, it does not dissolve in cold nitric acid because a protective film of gallium oxide forms on the surface.1
  • Reaction with Alkalis: The metal dissolves in alkalies, such as sodium or potassium hydroxide solutions. This process evolves hydrogen gas and results in the formation of gallates, such as [Ga(OH)4]βˆ’, where gallium exists within an anion.1