How does chlorine react with water to form chlorine water?

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Chlorine is moderately soluble in water, and this process yields a solution known as chlorine water.1

When chlorine gas dissolves in water, it undergoes a chemical reaction that results in the formation of both hydrochloric acid and hypochlorous acid. This reaction is a form of disproportionation, where one chlorine atom is oxidized and another is reduced, as represented by the following chemical equation:

Cl2+H2O⇌HOCl+HCl

In this process, the solution becomes acidic. Chlorine water is characterized as a yellowish aqueous solution that functions as an oxidizing agent, though its effectiveness in this capacity diminishes over time as the unstable hypochlorous acid gradually decomposes. Additionally, when this solution stands, a solid hydrate can be obtained, which features a structure more open than that of ice.123