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How does bonding in oxides change across a period of the periodic table?
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oxide
Iron oxide (rust) on a bolt.
Across a period of the periodic table, the bonding in oxides exhibits a smooth transition from ionic to covalent as one moves from the metals on the left to the nonmetals on the right.1
This progression is accompanied by a corresponding shift in the acid-base character of the oxides, which transitions from strongly basic to strongly acidic. The general trend is as follows:2
- Ionic Bonding: Typically found in oxides of metals on the left side of the table (e.g., alkali metals and alkaline earth metals). These compounds contain the oxide anion () and generally exhibit basic properties, reacting with water to form hydroxides.21
- Covalent Bonding: Found in oxides of nonmetals on the right side of the table. These are typically molecular in character and react with water to form acidic solutions.1
- Intermediate Character: As the bonding shifts toward covalent, the oxides may exhibit amphoteric behavior, meaning they can react as either an acid or a base.2
For example, in the third period, bonding progresses from ionic in and to covalent in , , , and .1