How does an electric current cause ions to form new substances during electrolysis?

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During electrolysis, an electric current drives chemical changes by forcing ions to migrate toward oppositely charged electrodes, where they undergo oxidation or reduction.12

When a direct current is applied to an electrolytic cell, the electrodes develop opposite polarities, causing the following process:

  • Migration: Positively charged ions move toward the negative electrode (cathode), while negatively charged ions move toward the positive electrode (anode).32
  • Electron Transfer: At the cathode, ions gain electrons (reduction) to become neutral atoms or new molecules. At the anode, ions transfer electrons to the electrode (oxidation), also forming neutral particles or new substances.13
  • Chemical Transformation: This discharge of ions at the electrode surfaces converts the charged particles into new chemical species, effectively using electrical energy to drive a chemical reaction that would not otherwise occur.32

Essentially, the current acts as a source of electrons that facilitates the transformation of ions into stable, neutral elements or compounds.12