How does ammonium chloride make an acidic solution in water?

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Ammonium chloride (NH4Cl) creates a slightly acidic solution in water through a process known as hydrolysis.12

Under the Brønsted–Lowry theory, this occurs because the ammonium ion (NH4+) acts as a weak acid. When the salt dissolves in water, the ammonium ion donates a proton (H+) to a water molecule (H2O), resulting in the formation of the hydronium ion (H3O+) and ammonia (NH3). The presence of these hydronium ions is what accounts for the acidity of the solution.23

The chloride ion (Cl−) does not participate in this reaction, as it is the conjugate base of a strong acid and possesses negligible acid–base properties in this context. This hydrolysis reaction is essentially the reverse of the neutralization of aqueous ammonia by a strong acid.23