How do the specific heat and thermal conductivity of a superconductor change near its transition temperature?

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Near the transition temperature (Tc), the thermal properties of a superconductor undergo distinct changes as the material shifts between states:

  • Specific Heat: The electronic specific heat in the superconducting state (Ces) is generally smaller than in the normal state (Cen) at low temperatures. However, as Tc is approached, Ces becomes larger than Cen. For classic superconductors, it drops abruptly to Cen at Tc, while high-Tc superconductors exhibit a cusp-like shape near the transition. This increase in Ces occurs because the energy gap decreases as the temperature rises, leading to an increase in the number of thermally excited electrons, which requires the absorption of heat.1

  • Thermal Conductivity: The thermal conductivity in the normal state (Kn) approaches the thermal conductivity in the superconducting state (Ks) as the temperature nears Tc. This convergence occurs for both pure and impure materials and suggests that the energy gap for each electron approaches zero as the temperature reaches the transition point.1