How do the melting points of alkaline-earth metals compare with those of alkali metals?
The melting points of alkaline-earth metals are higher than those of the corresponding alkali metals.1
While alkali metals are characterized by having some of the lowest melting points of any non-gaseous group in the periodic table—ranging from 179 °C for lithium to 28.5 °C for cesium—alkaline-earth metals are generally harder and possess higher melting points. For instance, magnesium has a melting point of 650 °C, and beryllium has the highest in its group at 1,287 °C.231
The lower melting points of alkali metals are a direct result of their loose crystallographic arrangement and the weak bond energies associated with their large interatomic distances. In contrast, the alkaline-earth metals exhibit stronger metallic bonding, contributing to their increased hardness and higher melting points compared to their neighbors in Group 1.213