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How do temperature and pressure affect whether matter is a solid, liquid, or gas?
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principles of physical science
Figure 1: Data in the table of the Galileo experiment. The tangent to the curve is drawn at t = 0.6.
The state of matterāsolid, liquid, or gasāis determined by the balance between the kinetic energy of a substance's particles and the forces of attraction acting between them. These states are mapped using a phase diagram, which illustrates how a substance transitions between phases based on changes in temperature and pressure.12
- Temperature: Increasing temperature adds heat, providing particles with the energy needed to overcome attractive forces. Heating a solid allows particles to move into a liquid state, while further heating provides the energy for liquid particles to escape into a gaseous state. Conversely, cooling a gas slows particle motion, allowing attractive forces to coalesce them into a liquid and eventually a solid.1
- Pressure: Pressure influences the density and spacing of particles. Higher pressure generally favors the more dense phase. For example, increasing pressure can force a gas to condense into a liquid.1324
At specific temperature and pressure combinations, two phases can exist in equilibrium, represented by lines on a phase diagram. The triple point is the unique condition where all three phases coexist.23