How do sodium and calcium ions affect the density of silica glass?

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In silica glass, the addition of sodium and calcium ions causes the density of the material to increase steadily.1

In its pure form, silica glass possesses a random atomic structure with relatively large interstitial spaces, or "holes," between atoms, which results in a lower density compared to its crystalline counterparts. When sodium and calcium are introduced as network-modifying ions, they occupy these interstitial spaces within the glass structure. As these ions fill the available free volume, the overall density of the glass increases. Consequently, commercial soda-lime-silica glasses exhibit a higher density than pure vitreous silica.12