How do oxidizing agents differ from reducing agents?

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In chemistry, oxidizing agents and reducing agents are defined by their opposing roles in oxidation-reduction reactions, which involve the transfer of electrons between chemical species.12

  • Oxidizing agents are substances that cause oxidation by accepting electrons from another species. Common examples include molecular oxygen, hydrogen peroxide, and halogens like chlorine and fluorine. In many reactions, they also serve as sources of oxygen atoms or acceptors of hydrogen atoms.341
  • Reducing agents are substances that cause reduction by donating electrons to another species. By providing these electrons, the reducing agent itself becomes oxidized.54

While these definitions are often centered on electron transfer, redox processes can also be characterized by the transfer of hydrogen atoms or oxygen atoms. In complex systems, such as coordination compounds, these transfers may occur through specific mechanisms, such as outer-sphere or inner-sphere pathways, depending on whether the coordination spheres of the involved complexes remain intact or undergo rearrangement.12