How do double bonds change the shape of an ethene molecule?
In the ethene (or ethylene) molecule, the presence of a double bond fundamentally dictates its geometry through hybridization.
Each carbon atom undergoes hybridization, where one and two orbitals mix to form three hybrid orbitals pointing toward the corners of an equilateral triangle. This results in a planar triangular arrangement around each carbon, with bond angles close to 120°.12
The double bond itself consists of a sigma bond and a pi bond. The pi bond is formed by the overlap of unhybridized orbitals that lie perpendicular to the plane of the triangle. Because this overlap is maximized when the orbitals are parallel, the double bond prevents free rotation around the carbon-carbon axis. This imparts torsional rigidity to the molecule, ensuring that ethene remains a flat, planar structure.314