Britannica
Sources used in this answer
How did the Downs cell process produce sodium metal from molten sodium chloride?
Created from Britannica articles
using AI.
AI can make mistakes, so verify using Britannica articles.
alkali metal
Modern version of the periodic table of the elements (printable).
The Downs cell process, introduced in 1926, replaced the earlier Castner process for the industrial production of sodium metal. In this method, a mixture of sodium chloride and calcium chloride is electrolyzed. The addition of calcium chloride is essential because it lowers the melting point of the salt mixture, allowing the process to operate more efficiently. During electrolysis, the molten mixture is dissociated to produce both sodium metal and chlorine gas.1