Britannica Sources used in this answer

How did the Downs cell process produce sodium metal from molten sodium chloride?

Created from Britannica articles using AI. AI can make mistakes, so verify using Britannica articles.

The Downs cell process, introduced in 1926, replaced the earlier Castner process for the industrial production of sodium metal. In this method, a mixture of sodium chloride and calcium chloride is electrolyzed. The addition of calcium chloride is essential because it lowers the melting point of the salt mixture, allowing the process to operate more efficiently. During electrolysis, the molten mixture is dissociated to produce both sodium metal and chlorine gas.1