How did radioactive decay help add argon to Earth’s atmosphere?

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Argon-40 (40Ar) is the most abundant noble gas in Earth’s atmosphere, a result of the radioactive decay of potassium-40 (40K), which is a common element in the planet's crustal rocks.123

Unlike primordial noble gases that were present during the Earth's formation, 40Ar is radiogenic. The process of its addition to the atmosphere occurs in several stages:13

  • Production: As radioactive 40K decays within rock-forming minerals, it produces 40Ar as a daughter product, which becomes trapped within the mineral crystal structures.123
  • Release: Through igneous activity, these rocks are melted, allowing the trapped argon gas to escape from the mineral lattice.3
  • Outgassing: The released gas eventually reaches the surface and is added to the atmosphere through the process of outgassing.3

Because the Earth trapped relatively little primordial argon during its accretion, this continuous accumulation of radiogenic 40Ar over geological time has caused it to dominate the isotopic composition of atmospheric argon, making it significantly more abundant on Earth than in the rest of the solar system.143