How did Niels Bohr explain the hydrogen spectrum?
In 1913, Niels Bohr proposed a model of the hydrogen atom that successfully explained its discrete line spectrum by incorporating quantum theory into the existing Rutherford model.21
Bohr postulated that electrons could only occupy a discrete set of circular orbits, known as stationary states, where they do not radiate energy. He assumed that an electron's angular momentum in these orbits must be a whole-number multiple of ().21
According to Bohr, light is emitted or absorbed only when an electron makes an abrupt transition between these allowed energy states. The frequency of the emitted or absorbed radiation is determined by the energy difference between the initial and final states:21
By applying these assumptions, Bohr derived the mathematical formula for the wavelengths of hydrogen's spectral lines, correctly calculating the Rydberg constant and providing a theoretical basis for empirical observations like the Balmer series.31