How can the ideal gas law be used for a mixture of gases?
The ideal gas law, expressed as , can be applied to a mixture of gases by defining as the total number of moles of all species present in the volume . In this context, is the sum of the moles of each individual component ().1
Alternatively, the law can be applied to each component individually to determine its partial pressure. The partial pressure of a specific gas () is the pressure it would exert if it alone occupied the total volume of the mixture at the same temperature, calculated as . According to Dalton’s law, the total pressure of the mixture is simply the sum of these individual partial pressures ().21
This approach assumes that the gases do not chemically interact and behave as ideal gases, which is a valid approximation for real gases at sufficiently low pressures and high temperatures.23