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How can heating magnetite in air change it into hematite?
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oxide
Iron oxide (rust) on a bolt.
Heating magnetite in air facilitates its transformation into hematite through an oxidation process.1
Magnetite contains both ferrous () and ferric () ions in a 1:2 ratio, whereas hematite is the fully oxidized form containing only ions. Because hematite is the most stable form of iron oxide in air, magnetite—which is stable primarily in low-oxygen environments—will undergo a chemical change to hematite when exposed to heat or air for a prolonged period. This redox behavior is a fundamental property of iron oxides, where heating or exposure to oxidizing gases drives the transition toward the more stable, fully oxidized state.12