How can absorbed light cause a molecule to display a particular color?
The color of a molecule is a human observation of the inverse of its visible absorption spectrum. When a molecule absorbs specific wavelengths of visible light, it promotes an electron from a lower-energy molecular orbital to a higher-energy, unoccupied orbital. The energy difference () between these orbitals determines which frequencies of light are absorbed.12
The perceived color is the light that remains after the molecule has absorbed its characteristic frequencies. For example, a compound that absorbs light in the violet-blue region will appear yellow to the eye.12
The ability to absorb visible light often depends on the molecule's structure:
* Conjugated systems: Many organic compounds with extensive systems of conjugated bonds absorb visible light, which can result in intense colors, such as the blue of azulene or the orange of -carotene.3
* Transition metals: Coordination compounds containing transition elements often exhibit color due to electronic transitions involving d-level atomic orbitals.2
Molecules that only absorb in the ultraviolet region appear colorless or white because they do not interact with visible light.23