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How are the atoms arranged around the double bond in ethene?
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organic compound
The structures of organic compounds can be depicted in condensed, expanded, and three-dimensional structural formulas.
In the ethene (also known as ethylene) molecule, the six atoms involved in the double bond lie in a single plane.12
The arrangement around each carbon atom is as follows:
- Planar Geometry: Each carbon atom is bonded to two hydrogen atoms and one other carbon atom. These three bonding regions adopt a planar triangular arrangement, with bond angles (H–C–H and H–C=C) predicted to be close to 120°.2
- Hybridization: This structure is explained by hybridization, where one and two orbitals of each carbon atom mix to form three hybrid orbitals pointing toward the corners of an equilateral triangle.3
- Bonding: The three hybrid orbitals form (sigma) bonds with the two hydrogen atoms and the other carbon atom. The remaining unhybridized orbital on each carbon lies perpendicular to this plane, overlapping side-by-side to form a (pi) bond.3
This planar configuration confers torsional rigidity to the molecule, as twisting the structure would reduce the overlap of the orbitals and weaken the bond.3