How are the atoms arranged around the double bond in ethene?

Created from Britannica articles using AI. AI can make mistakes, so verify using Britannica articles.

In the ethene (also known as ethylene) molecule, the six atoms involved in the double bond lie in a single plane.12

The arrangement around each carbon atom is as follows:

  • Planar Geometry: Each carbon atom is bonded to two hydrogen atoms and one other carbon atom. These three bonding regions adopt a planar triangular arrangement, with bond angles (H–C–H and H–C=C) predicted to be close to 120°.2
  • Hybridization: This structure is explained by sp2 hybridization, where one 2s and two 2p orbitals of each carbon atom mix to form three hybrid orbitals pointing toward the corners of an equilateral triangle.3
  • Bonding: The three sp2 hybrid orbitals form σ (sigma) bonds with the two hydrogen atoms and the other carbon atom. The remaining unhybridized 2p orbital on each carbon lies perpendicular to this plane, overlapping side-by-side to form a π (pi) bond.3

This planar configuration confers torsional rigidity to the molecule, as twisting the structure would reduce the overlap of the 2p orbitals and weaken the π bond.3