Britannica
Sources used in this answer
How are epoxides made from alkenes using peroxyacids?
Created from Britannica articles
using AI.
AI can make mistakes, so verify using Britannica articles.
Epoxides are cyclic ethers containing a three-membered ring with one oxygen atom attached to two adjacent carbon atoms. On a laboratory scale, they are typically synthesized through the epoxidation of alkenes using a peroxyacid (represented by the general formula ).12
In this reaction, the peroxyacid acts as an oxidizing agent, transferring an oxygen atom directly to the alkene to form the epoxide ring. Peroxyacids are characterized by the presence of the group, which replaces the group found in standard oxy acids. Because of the strain inherent in the three-membered ring, the resulting epoxides are significantly more reactive than typical acyclic ethers, making them valuable intermediates for various chemical transformations.13