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How are binary ionic compounds named?
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chemical compound
Methane, in which four hydrogen atoms are bound to a single carbon atom, is an example of a basic chemical compound. The structures of chemical compounds are influenced by complex factors, such as bond angles and bond length.
The nomenclature for binary ionic compoundsâcompounds consisting of two different elementsâfollows a standardized set of rules based on the names of the constituent ions.12
Naming Rules
- Cation First: The positive ion (cation) is named first, followed by the negative ion (anion).12
- Cation Name: A simple cation derived from a single atom retains the name of its parent element (e.g., is sodium).12
- Anion Name: A simple anion is named by taking the root of the parent element's name and adding the suffix -ide (e.g., becomes chloride).12
Metals with Multiple Charges
When a metal can form more than one type of cation, the specific charge must be indicated using a Roman numeral in parentheses immediately following the metal's name. For example, is named iron(III) chloride, while is iron(II) chloride.12
Older nomenclature may use the suffixes -ic for the higher charge and -ous for the lower charge (e.g., ferric chloride and ferrous chloride, respectively).12