How are binary ionic compounds named?

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The nomenclature for binary ionic compounds—compounds consisting of two different elements—follows a standardized set of rules based on the names of the constituent ions.12

Naming Rules

  1. Cation First: The positive ion (cation) is named first, followed by the negative ion (anion).12
  2. Cation Name: A simple cation derived from a single atom retains the name of its parent element (e.g., Na+ is sodium).12
  3. Anion Name: A simple anion is named by taking the root of the parent element's name and adding the suffix -ide (e.g., Cl− becomes chloride).12

Metals with Multiple Charges

When a metal can form more than one type of cation, the specific charge must be indicated using a Roman numeral in parentheses immediately following the metal's name. For example, FeCl3 is named iron(III) chloride, while FeCl2 is iron(II) chloride.12

Older nomenclature may use the suffixes -ic for the higher charge and -ous for the lower charge (e.g., ferric chloride and ferrous chloride, respectively).12