Why did Mariner 10 photograph only part of Mercury’s surface?

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Mariner 10 was able to photograph only about 45 percent of Mercury’s surface because of the specific orbit the spacecraft followed around the Sun.1

The spacecraft was placed in a solar orbit that matched one Mercurian solar day. As a result, each of the three flybys occurred when the exact same hemisphere of the planet was illuminated by sunlight. Consequently, the mission could only capture images of the sunlit side, leaving the remainder of the surface unmapped by the probe.1