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Which volcano is the tallest on Mars and in the solar system?

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The tallest volcano on Mars and in the entire solar system is Olympus Mons.

This massive shield volcano stands approximately 22 km (14 miles) high and spans 700 km (435 miles) across. Its immense size is attributed to the stability of the Martian crust and a long period of volcanic activity, potentially spanning over a billion years.1