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Which state challenged the federal government during the Nullification Crisis?

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The state that challenged the federal government during the Nullification Crisis of 1832–1833 was South Carolina.21

Driven by the political influence of John C. Calhoun, the state adopted the Ordinance of Nullification in November 1832, declaring federal tariffs null and void within its borders. This action was based on the constitutional theory that states possessed the right to nullify federal acts they deemed unconstitutional. The crisis concluded after President Andrew Jackson asserted the supremacy of the federal government and Congress passed the Force Bill, leading South Carolina to rescind its ordinance.21